Hydrogen fine structure

What you are seeing: the relativistic + spin-orbit fine-structure correction splits hydrogen levels by total angular momentum $j$ rather than orbital $\ell$. The 2s/2p degeneracy of Bohr lifts: 2p$_{3/2}$ moves up, 2s$_{1/2}$ and 2p$_{1/2}$ stay degenerate (Lamb shift is excluded here, see Lamb playground).